Isaac Scientific Publishing

Journal of Advances in Applied Physics

Characterization of Titanium Dioxide Coatings Obtained by Vacuum-arc Deposition

Download PDF (1910.4 KB) PP. 1 - 8 Pub. Date: February 1, 2020

DOI: 10.22606/jaap.2020.21001

Author(s)

  • Anton Taran*
    National Science Center “Kharkov Institute of Physics and Technology” (NSC KIPT), Institute of Plasma Physics, Kharkov, Ukraine
  • Igor Garkusha
    National Science Center “Kharkov Institute of Physics and Technology” (NSC KIPT), Institute of Plasma Physics, Kharkov, Ukraine; Karazin State University, Kharkov, Ukraine
  • Alexander Timoshenko
    National Science Center “Kharkov Institute of Physics and Technology” (NSC KIPT), Institute of Plasma Physics, Kharkov, Ukraine
  • Valerij Taran
    National Science Center “Kharkov Institute of Physics and Technology” (NSC KIPT), Institute of Plasma Physics, Kharkov, Ukraine
  • Ivan Misiruk
    National Science Center “Kharkov Institute of Physics and Technology” (NSC KIPT), Institute of Plasma Physics, Kharkov, Ukraine
  • Tamara Skoblo
    National Technical University of Agriculture, Kharkov, Ukraine
  • Svetlana Romaniuk
    National Technical University of Agriculture, Kharkov, Ukraine
  • Taras Maltsev
    National Technical University of Agriculture, Kharkov, Ukraine
  • Vadym Starikov
    National Technical University “Kharkov Polytechnical Institute”,Kharkov, Ukraine
  • Alexey Baturin
    National Technical University “Kharkov Polytechnical Institute”,Kharkov, Ukraine
  • Yurij Gnidenko
    Karazin State University, Kharkov, Ukraine

Abstract

TiO2 coatings on AISI 430 stainless steel were produced by the vacuum-arc deposition technique with the application of modified curvilinear magnetic filter allowed enhanced deposition rates up to 50 μm/ hour decreasing the amount of macroparticles. The structure, chemical and phase composition of the obtained coatings was investigated using SEM with EDX, XRF and XRD analysis. According to X-ray diffraction analysis, the formation of stoichiometric TiO2 phase took place. The mechanical and tribological properties were established. The obtained coatings had average nanohardness of 13.8 GPa and Young’s modulus of 211 GPa. Dry friction wear tests revealed high resistance of the coating to wear showing low friction coefficient under a load of 50 N. The statistical results of photo-catalytic activity showed a significant decrease of E.coli colonies on samples coated with TiO2 during 20 min UV exposure format.

Keywords

Titanium dioxide, structure, vacuum-arc deposition, coating, phase composition, nanohardness, photocatalytic activity

References

[1] N. Berger-Keller, G. Bertrand, C. Filiatre, C. Meunier, C. Coddet, “Microstructure of Plasma sprayed titania coatings deposited from spray-dried powder”,Journal Surface and Coatings Technology, vol. 168(2-3), pp.281- 290, 2003.

[2] M. Anpo, “Preparation, Characterization, and Reactivities of Highly Functional Titanium Oxide-Based Photocatalysts Able to Operate under UV–Visible Light Irradiation: Approaches in Realizing High Efficiency in the Use of Visible Light,” Bulletin of the Chemical Society of Japan, vol. 77, no. 8, pp. 1427–1442, 2004.

[3] N.R. Mathews, E.R. Morales, M.A. Cortes-Jacome, J.A.T. Antonio, “TiO2 thin films – Influence of annealing temperature on structural, optical and photocatalytic properties”, Journal of Solar Energy, vol.83, pp.1499-1508, 2009.

[4] C.J. Chung, H.I. Lin, H.K. Tsou, Z.Y. Shi, J.L. He, “An antimicrobial TiO2 coating for reducing hospitalacquired infection”, J Biomed Mater Res B Appl Biomater, vol. 85(1), pp. 220-4. 2008

[5] N. Martin, C. Rousselot, D. Rondot, F. Palmino and R. Mercier, “Microstructure modification of amorphous titanium oxide thin films during annealing treatment,” Journal Thin Solid Films, vol. 300, no.1-2, pp.113-121, 1997

[6] M. Takeuchi, T. Yamasaki, K. Tsujimaru, “Preparation of TiO2 thin film photocatalyst on polycarbonate substrates by a RF-magnetron sputtering method”, Journal of Chem. Lett., vol.35, pp. 904-905, 2006

[7] B.M. Reddy, G.K. Reddy, I. Ganesh, J.M.F. Ferreira, “Single step synthesis of nanosized CeO2–MxOy mixed oxides (MxOy = SiO2, TiO2, ZrO2, and Al2O3) by microwave induced solution combustion synthesis: characterization and CO oxidation”, Journal Mater. Sci, vol. 44, pp. 2743–2751, 2009

[8] M.Thaidun, B. Venkata Rao, L. Raja Mohan Reddy, “Surface Morphological and Electrical Properties of Sputtered TiO2 Thin Films”, Journal of Applied Physics, vol. 4, no. 1, pp. 25-29, 2013

[9] M. Vishwas, S.K. Sharma, K. Narshimha Reao, S. Mohan,K.V.A. Gowda and R.P.S. Chakradhar, Spectrochim, “Influence of surfactant and annealing temperature on optical properties of sol-gel derived nano-crystalline TiO2 thin films”, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 75, no. 3, pp.1073- 1077, 2010.

[10] T.S. Skoblo, S.P. Romaniuk, A.I. Sidashenko, I.E. Garkusha, V.S. Taran, A.V. Taran, N.N. Pilgui “Strengthening method for thin-walled knives with multi-layer nanocoatings and quality assessment by nondestructive method”, Journal of Advanced Microscopy Research. vol.13, no.3, pp. 333–338, 2018.

[11] Valerij S. Taran, Rinat M. Muratov, and Anton V. Taran, “Spectrophotometric Evaluation of Reflection Coefficient of Thin Ti and TiN Coatings Depending on Deposition Method”, Journal of Advanced Microscopy Research, vol. 12, pp. 203–206, 2017

[12] V.S. Taran, I.E. Garkusha, “Recent developments of plasma-based technologies for medicine and industry”, Journal Nukleonika., vol. 57, no.2, pp. 277-282, 2012

[13] V.V. Gasilin, V.V. Kunchenko, Yu.N. Nezovybat’ko, A.V. Taran, V.S. Taran, V.I. Tereshin, O.M. Shvets, “Production of metal and dielectric films in a combined RF and arc discharge”, J. Problems of Atomic Science and Technology, vol.1, pp.157-159, 2003

[14] T.S. Skoblo, S.P. Romaniuk, A.I. Sidashenko, I.E. Garkusha, V.S. Taran, A.V. Taran, R.M. Muratov “Surface Morphology and Mechanical Properties of Vacuum-Arc Evaporated CrN and TiN Coatings on Cutting Tool”, Journal of Advanced Microscopy Research, vol. 13, no.4, р.477-481, 2018.